First duplicate the layer:
![](http://web.shepherdpics.com/Blog/uploaded_images/Chrome1-740156.jpg)
Run the High-Pass filter with a large number of pixels so that the shiny areas get emphasised.
![](http://web.shepherdpics.com/Blog/uploaded_images/Chrome2-702885.jpg)
Finally then just change the layer blend mode to soft-light ( or hard-light) to make it all shiny:
Related Posts
Beginners guide to Photoshop Layers:
Part 1
Part 2
Part 3
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